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Showing 1–3 of 3 results
Advanced filters: Author: Filipe Junqueira Clear advanced filters

  • Charge transfer is facilitated in molecular systems through orbital coupling. Here the authors use core-hole-clock spectroscopy to show that electron transfer from an argon atom caged in a fullerene can be up to two orders of magnitude faster than for the isolated atom.

    • Connor Fields
    • Aleksandra Foerster
    • Philip Moriarty
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-10

  • The chemical nature of molecules encapsulated within fullerenes remain debated, with reports proposing a Faraday cage effect. Here, the authors show that H2O and HF molecules encapsulated inside a C60 cage experience a substantial intra-cage electrostatic interaction that results in off-center locations; despite this, the endofullerene’s frontier orbitals is unaffected, resulting in chemical shielding of the caged molecule.

    • Samuel P. Jarvis
    • Hongqian Sang
    • Robert G. Jones
    ResearchOpen Access
    Communications Chemistry
    Volume: 4, P: 1-7

  • Ullmann-type reactions on metal surfaces are widely studied examples of on-surface synthesis. Here the combination of normal incidence X-ray standing wave analysis, X-ray photoelectron spectroscopy, and scanning tunneling microscopy enables the characterisation of molecular conformations in two such reactions.

    • Chris J. Judd
    • Filipe L. Q. Junqueira
    • Alex Saywell
    ResearchOpen Access
    Communications Chemistry
    Volume: 3, P: 1-8