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Showing 1–3 of 3 results
Advanced filters: Author: Fiona Hanindita Clear advanced filters

  • Heterofullerenes are an important synthetic target for organic chemists. Here, the authors demonstrate a fully conjugated azacorannulene dimer starting from a bifunctional polycyclic aromatic azomethine ylide, providing a powerful method for the bottom-up synthesis of large multiazafullerene fragments

    • Weifan Wang
    • Fiona Hanindita
    • Shingo Ito
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-7

  • Heteroatom-embedded hexa-peri-hexabenzocoronenes (HBCs) display notable properties, but the selective incorporation of heteroatoms into the HBC core makes their synthesis difficult. Now a two-step process for the synthesis of 3a2-azahexabenzocoronenium salts is reported. The process comprises a formal [3 + 3] cycloaddition between azomethine ylides and cyclopropenes, followed by mechanochemical cyclization.

    • Xinjiang Zhang
    • Donglin Li
    • Shingo Ito
    Research
    Nature Synthesis
    Volume: 3, P: 1283-1291