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Showing 1–11 of 11 results
Advanced filters: Author: Franc Meyer Clear advanced filters

  • Noble metals dominate the field of photosensitizers and luminophores. Now, an approach incorporating cyclometalating and carbene functions into FeIII complexes has been shown to enable dual emission from the opposing ligand-to-metal and metal-to-ligand charge-transfer states. The latter shows an exceptionally long lifetime of 4.6 ns and is quenched by oxygen and other quenchers.

    • Jakob Steube
    • Ayla Kruse
    • Matthias Bauer
    ResearchOpen Access
    Nature Chemistry
    Volume: 15, P: 468-474

  • Attempts to bend and twist multiple bonds in order to alter their reactivities have thus far been met with only modest success. Here, Braunschweig and colleagues isolate double-bond-containing boron-based species and their 90°-twisted diradical analogs, thanks to their stabilization with Lewis basic units.

    • Julian Böhnke
    • Theresa Dellermann
    • Holger Braunschweig
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-7

  • [NiFe] hydrogenases are enzymes containing nickel and iron centres that catalyse hydrogen evolution with performances that rival those of platinum catalysts. Now, a NiFe model complex has been reported that mimics the structure and the Ni-centred hydrogen evolution activity found at the active site of [NiFe] hydrogenases.

    • Deborah Brazzolotto
    • Marcello Gennari
    • Carole Duboc
    Research
    Nature Chemistry
    Volume: 8, P: 1054-1060

  • Adult forms of inflammatory bowel disease (IBD) are of a polygenic nature, but paediatric and very early onset (VEO) IBD also occur as monogenic forms. Here, using whole exome sequencing, the authors explore both the monogenic and polygenic contribution to VEO-IBD and characterize a rare somatic mosaic VEO-IBD patient.

    • Eva Gonçalves Serra
    • Tobias Schwerd
    • Carl A. Anderson
    ResearchOpen Access
    Nature Communications
    Volume: 11, P: 1-15

  • This study describes a premotor-hippocampal coupling in episodic memory, revealing how the bodily sensory context and in particular the sense of agency of the observer at encoding is neurally reinstated during the retrieval of past episodes.

    • Nathalie Heidi Meyer
    • Baptiste Gauthier
    • Olaf Blanke
    ResearchOpen Access
    Communications Biology
    Volume: 7, P: 1-19

  • Thiolate groups are promising anchors to immobilize catalysts, particularly on coinage metal surfaces, but the anchor group’s impact on the local adsorption configuration of the catalyst is often overlooked. Here, the authors study a sulfurated derivative of the prominent Re(bpy)(CO)3Cl carbon dioxide reduction catalysts on a Ag(001) surface at room temperature.

    • Ole Bunjes
    • Alexandra Rittmeier
    • Martin Wenderoth
    ResearchOpen Access
    Communications Chemistry
    Volume: 7, P: 1-8

  • A stochastic background of gravitational waves is expected to arise from a superposition of a large number of unresolved gravitational-wave sources and should carry unique signatures from the earliest epochs of the Universe. Limits on the amplitude of the stochastic gravitational-wave background are now reported using the data from a two-year science run of the Laser Interferometer Gravitational-wave Observatory. These limits rule out certain models of early Universe evolution.

    • B. P. Abbott
    • R. Abbott
    • J. Zweizig
    Research
    Nature
    Volume: 460, P: 990-994