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Slow vibrational relaxation drives ultrafast formation of photoexcited polaron pair states in glycolated conjugated polymers

Glycol sidechains are often used to enhance the performance of organic photoconversion and electrochemical devices. Here, the authors provide photophysical insight into the role of glycol sidechains for the formation of polaron pairs induced by strong vibrational coupling.

Katia Pagano
Jin Gwan Kim
Ji-Seon Kim
ResearchOpen Access22 Jul 2024
Nature Communications

Volume: 15, P: 1-13
A versatile high-average-power ultrafast infrared driver tailored for high-harmonic generation and vibrational spectroscopy

Nicolas Thiré
Gourab Chatterjee
Nicolas Forget
ResearchOpen Access01 Nov 2023
Scientific Reports

Volume: 13, P: 1-6
Three-dimensional covariance-map imaging of molecular structure and dynamics on the ultrafast timescale

Ultrafast laser pump-probe methods allow chemical reactions to be followed in real-time, but to directly show the rearrangement of nuclear frameworks is challenging. Here an improved real-time-resolved 3D covariance-map Coulomb explosion imaging technique for ultrafast gas-phase reactions is presented.

Jason W. L. Lee
Hansjochen Köckert
Claire Vallance
ResearchOpen Access05 Jun 2020
Communications Chemistry

Volume: 3, P: 1-6

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