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Showing 1–3 of 3 results
Advanced filters: Author: Gebhard Haberhauer Clear advanced filters

  • Cryptophanes are common host molecules, capable of binding neutral guests strongly. Here the authors show that, contrary to popular belief, solvents commonly used for these studies can be enclosed by the host and hence affect the calculated binding constants.

    • Gebhard Haberhauer
    • Sascha Woitschetzki
    • Heinz Bandmann
    Research
    Nature Communications
    Volume: 5, P: 1-7

  • Typically dispersion forces are weak interactions, and host–guest chemistry is dominated by more powerful events such as hydrogen bonding. Here, the authors show extremely high binding between a modified marine peptide and chloroform, driven by dispersion interactions with the chlorine atoms.

    • Gebhard Haberhauer
    • Áron Pintér
    • Sascha Woitschetzki
    Research
    Nature Communications
    Volume: 4, P: 1-8

  • The synthesis, structure and reactivity of room-temperature-stable [Cp(C6F5)5]+[Sb3F16]− is presented. Coordination of the cyclopentadienyl cation by [Sb3F16]− or C6F6 stabilizes the antiaromatic singlet state in the solid state. Calculated hydride and fluoride ion affinities of the [Cp(C6F5)5]+ cation are higher than those of the tritylium cation [C(C6F5)3]+.

    • Yannick Schulte
    • Christoph Wölper
    • Stephan Schulz
    Research
    Nature Chemistry
    Volume: 16, P: 651-657