Spinodal decomposition, spontaneous phase separation process for periodic lamellae at the nanometer scale, of correlated oxides (Ti, V)O2 systems offers a sophisticated route to achieve new class of mesoscale structure in the form of self-assembled superlattices. Here, we achieve the tunable self-assembly of (Ti, V)O2 superlattices with steep metal-insulator transition (ΔTMI < 5 K) by spinodal decomposition with accurate control of growth parameters. Increase in a film growth rate thickens a lamellae period; the phase separation were kinetically enhanced by adatom impingement during two-dimensional growth, demonstrating that interplay between mass transport and uphill diffusion yields highly periodic (Ti, V)O2 superlattices.
- Jaeseoung Park
- Gi-Yeop Kim
- Junwoo Son