The carboamination of unsaturated molecules with bifunctional carboamination reagents is considered to be an attractive approach for the synthesis of nitrogen-containing compounds but employing bifunctional C–N reagents in the functionalization of cyclopropane remains underdeveloped. Here the authors present N-heterocyclic carbenes and a photoredox catalyst dualcatalyzed 1,3-aminoacylation of cyclopropane employing N-benzoyl saccharin as a bifunctional reagent.
- Mingrui Li
- Yingtao Wu
- Qian Zhang