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Copper integrative catalytic pairs with mixed-valence Cu²⁺-Cu³⁺ Species for selective alkyne conversion

Selective alkyne transformations via precise orbital activation remain challenging. Here, O-bridged Cu catalytic pairs boost acetylene hydrochlorination by tailored orbital coupling, shifting reaction pathways and lowering energy barriers.

Yuxue Yue
Mingde Yu
Jia Zhao
ResearchOpen Access30 Oct 2025
Nature Communications

Volume: 16, P: 1-15

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Copper integrative catalytic pairs with mixed-valence Cu2+-Cu3+ Species for selective alkyne conversion

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Copper integrative catalytic pairs with mixed-valence Cu²⁺-Cu³⁺ Species for selective alkyne conversion