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Showing 1–5 of 5 results
Advanced filters: Author: Harry Mönig Clear advanced filters
  • Synthesis of aromatic belts with embedded thiophene structures, which manifest significant optoelectronic and conductive properties, has not yet been achieved. Herein, the authors report the synthesis of thiophene-fused aromatic belts via one-step sulfur cross-linking reaction of partially fluorinated cycloparaphenylenes.

    • Hiroki Shudo
    • Philipp Wiesener
    • Kenichiro Itami
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-9
  • Monomeric N-heterocyclic carbenes (NHCs) can act as molecular modifiers of metal surfaces and thus affect heterogeneous catalytic behaviour. Now NHC polymers have been formed on gold surfaces, consisting of ballbot-type repeating units bound to single gold adatoms. Conformational, electronic and charge transport properties explain the high surface mobility of the incommensurate NHC polymers.

    • Jindong Ren
    • Maximilian Koy
    • Frank Glorius
    Research
    Nature Chemistry
    Volume: 15, P: 1737-1744
  • On-surface dehydrogenative bond formation between sp3-hybridized carbon atoms usually requires high temperatures. Now, it has been shown that the higher homologue, silicon, can undergo dehydrogenative polymerization at room temperature on metal surfaces. This process creates well-ordered structures on Au(111) and Cu(111), with different stereoselectivity depending on the metal.

    • Lacheng Liu
    • Henning Klaasen
    • Armido Studer
    Research
    Nature Chemistry
    Volume: 13, P: 350-357