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Showing 1–4 of 4 results
Advanced filters: Author: Huanfeng Shen Clear advanced filters

  • Carboxylates are ideal directing groups for aryl C–H functionalizations, given their wide availability and relative ease of functional group interconversion; however, their potential in meta-selective functionalizations has not been fully realized. Here, the authors use carboxylates for meta-selective alkylations via ruthenium catalysis.

    • Xianglin Luo
    • Peichao Hou
    • Liangbin Huang
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-10

  • Molecular rearrangements are ubiquitous in modern synthetic chemistry, providing a powerful strategy to arrive at complex structures in an atom- and step-economic process. Here, the authors disclose a Mn(I)- catalyzed sigmatropic rearrangement of β, γ-unsaturated alcohols via C-C σ-bond activation to site-selectively reorganize carbon skeletons.

    • Can Yang
    • Xiaoyu Zhou
    • Wei Zeng
    ResearchOpen Access
    Nature Communications
    Volume: 14, P: 1-10

  • A digital twin of Earth would fully integrate Big Data observations within an Earth–human system model, to assess the interactions between these subsystems. This Review explores the current progress in Big Data manipulation in Earth sciences providing pathways toward digital twins of Earth.

    • Xin Li
    • Min Feng
    • Huadong Guo
    Reviews
    Nature Reviews Earth & Environment
    Volume: 4, P: 319-332