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Showing 1–17 of 17 results
Advanced filters: Author: Jeffrey A. Reimer Clear advanced filters

    • JEffREY A. GRAY
    Research
    Nature
    Volume: 349, P: 469

  • Controlling nuclear spin patterns is important to manage decoherence and control electron spin currents in spintronic devices. This study demonstrates the optical creation of rewritable patterns of nuclear polarization in gallium arsenide without ferromagnets, lithographic patterning or field gradients.

    • Jonathan P. King
    • Yunpu Li
    • Jeffrey A. Reimer
    Research
    Nature Communications
    Volume: 3, P: 1-7

  • Data mining of a computational library of metal–organic frameworks identifies motifs that bind CO2 sufficiently strongly and whose uptake is not affected by water, with application for the capture of CO2 from flue gases.

    • Peter G. Boyd
    • Arunraj Chidambaram
    • Berend Smit
    Research
    Nature
    Volume: 576, P: 253-256

  • Topochemical polymerization (TCP) emerges as a leading approach for synthesizing single crystalline polymers, but the untapped potential of performing TCP in a liquid medium with solid-state structural fidelity presents unsolved challenges. Here, the authors reveal details of single-crystal-to-single-crystal transformation during the TCP of chiral azaquinodimethane monomers through in situ crystallographic analysis while spotlighting a rare metastable crystalline phase.

    • Chongqing Yang
    • Jianfang Liu
    • Yi Liu
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-10

  • Defects in metal-organic frameworks impact their structure and properties. Here authors uncover formate defects in MOF-74 that originate from decomposed DMF solvent. NMR shows that the defects partially eliminate open metal sites and lead to a decrease of gas adsorption; the adsorption mechanism of CO2 in defective MOF is also elucidated.

    • Yao Fu
    • Yifeng Yao
    • Xueqian Kong
    ResearchOpen Access
    Nature Communications
    Volume: 14, P: 1-9

  • A framework that integrates materials, process design, techno-economics and life-cycle assessment can be used to accelerate the development of carbon-capture technology as we aim for a net-zero world.

    • Charithea Charalambous
    • Elias Moubarak
    • Susana Garcia
    ResearchOpen Access
    Nature
    Volume: 632, P: 89-94

  • A polymer semiconductor/ionic-liquid nanocomposite exhibiting mixed conduction is reported. Using operando X-ray scattering, dynamic structural changes are observed on electrochemical charging, which enables efficient electronic transport.

    • Tyler J. Quill
    • Garrett LeCroy
    • Christopher J. Takacs
    Research
    Nature Materials
    Volume: 22, P: 362-368

  • Solid acid heterogeneous catalysts are widely used in industrial chemical processes, but understanding the exact molecular structures responsible for catalytic activity has proved difficult. Now, the structure of the strong Brønsted acid site for a sulfated zirconium-based metal–organic framework has been shown to consist of a specific arrangement of adsorbed water and sulfate moieties on the zirconium clusters.

    • Christopher A. Trickett
    • Thomas M. Osborn Popp
    • Omar M. Yaghi
    Research
    Nature Chemistry
    Volume: 11, P: 170-176

  • Topochemical polymerization reactions produce ultra-high molecular weight crystalline polymers. Here the authors show a family of para-azaquinodimethane compounds that undergo facile visible light and thermally initiated polymerization in the solid state and the crystal structure has been resolved via cryoelectron microscopy.

    • Christopher L. Anderson
    • He Li
    • Yi Liu
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-8

  • Nitrogenases use transition metals to selectively capture weak π acids such as N2 by employing backbonding interactions. Here, a metal–organic framework with exposed vanadium sites is presented that uses this approach for selective capture of N2 from CH4, with impressive selectivity and capacity.

    • David E. Jaramillo
    • Douglas A. Reed
    • Jeffrey R. Long
    Research
    Nature Materials
    Volume: 19, P: 517-521

  • It's sometimes difficult to observe combustion in situ — inside, say, a porous material or an industrial reactor. But with the help of nuclear magnetic resonance, a new vista has opened up.

    • Jeffrey Reimer
    News & Views
    Nature
    Volume: 426, P: 508-509

  • Engineering of the coupling between optical modes in a lithium niobate chip enables the realization of tunable, bi-directional and low-loss electro-optic frequency shifters controlled using only continuous and single-tone microwaves.

    • Yaowen Hu
    • Mengjie Yu
    • Marko Lončar
    Research
    Nature
    Volume: 599, P: 587-593

  • Carbon capture and storage (CCS) can reduce emissions from coal-fired power plants (CFPPs) but it needs additional power that increases water use for plant cooling. This study models the impacts of retrofitting CFPPs with CCS on water resources globally and finds areas at risk of water scarcity.

    • Lorenzo Rosa
    • Jeffrey A. Reimer
    • Paolo D’Odorico
    Research
    Nature Sustainability
    Volume: 3, P: 658-666