Hydrogen spillover, a phenomenon typically associated with hydrogenation reactions over supported metal catalysts, has rarely been observed in molecular catalysts. Here, the authors highlight the crucial role of hydrogen spillover in the asymmetric hydrogenation of quinolines, utilizing a hybrid system consisting of metal nanoparticles and a chiral organometallic complex.
- Yiqi Ren
- Xin Liu
- Qihua Yang
