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Showing 1–2 of 2 results
Advanced filters: Author: Johannes E. Leisen Clear advanced filters
  • The most common oxidation state for lanthanide elements is +3, and, beyond cerium, examples of these elements exhibiting higher oxidation states remain scarce. Now, a molecular complex of praseodymium in the +5 oxidation state has been synthesized; this compound exhibits a unique electronic structure driven by N 2p and Pr 4f orbital contributions.

    • Andrew C. Boggiano
    • Chad M. Studvick
    • Henry S. La Pierre
    Research
    Nature Chemistry
    Volume: 17, P: 1005-1010
  • Chemical functionalization of the outer surfaces of single-walled nanotubes is well documented but internal modification is less well explored. Here, the authors fabricate single-walled metal oxide nanotubes with covalently bonded amines on their inner walls and study their gas adsorption properties.

    • Dun-Yen Kang
    • Nicholas A. Brunelli
    • Sankar Nair
    Research
    Nature Communications
    Volume: 5, P: 1-9