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Showing 1–3 of 3 results
Advanced filters: Author: Kami L. Hull Clear advanced filters

  • Biologically active compounds often contain a chiral centre in proximity of amine groups. Here, the authors developed a strategy involving asymmetric isomerization of allylic amines, enamine exchange and chemoselective reduction for the one-pot highly enantioselective synthesis of gamma-branched amines.

    • Zhao Wu
    • Summer D. Laffoon
    • Kami L. Hull
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-7

  • Many useful chemical scaffolds include carbon or nitrogen substitutions at two or three atoms away from benzene. Here, the authors show a unified hydroalkylation and hydroaminoalkylation protocol to access these structures via a regioselective photocatalytic addition to simple styrenes.

    • Zhao Wu
    • Samuel N. Gockel
    • Kami L. Hull
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-9

  • Aminopalladation is a key step in a number of carbon–nitrogen bond-forming processes, but carrying out this step with intermolecular anti-Markovnikov selectivity has remained difficult. Such a process has now been developed by using an anionic palladium catalyst to generate terminal carbon–nitrogen bonds from alkenes.

    • Daniel G. Kohler
    • Samuel N. Gockel
    • Kami L. Hull
    Research
    Nature Chemistry
    Volume: 10, P: 333-340