Adding rod-like low-mass molecules (LMs) increases the elastic modulus of polycarbonate (PC). The anisotropy of the rotational dynamics of rod-like LMs in PC was investigated by dielectric relaxation and dynamic mechanical analysis. Two rotations of the LM around the short and long axes were separately observed at 80 °C and −100 °C, respectively. The rotation of the LM around the short axis was cooperative with the local dynamics of PC and. In contrast, the rotational motion around the long axis was independent of PC motions.
- Mai Maeda
- Shogo Nobukawa
- Katsuhiro Inomata