Understanding reversible anionic redox reactions is key to designing high-energy-density cathodes for lithium-ion batteries. Anionic redox activation in cation-disordered rock-salt Li1.17Ti0.58Ni0.25O2 is shown to involve intermediate Ni3+/4+ species that can evolve to Ni2+ during relaxation.
- Biao Li
- Khagesh Kumar
- Jean-Marie Tarascon
