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Showing 1–4 of 4 results
Advanced filters: Author: Kuangbiao Liao Clear advanced filters
  • The idea of carbon–hydrogen functionalization, in which C–H bonds are modified at will, represents a paradigm shift in the standard logic of organic synthesis; here, dirhodium catalysts are used to achieve highly site-selective, diastereoselective and enantioselective C–H functionalization of n-alkanes and terminally substituted n-alkyl compounds.

    • Kuangbiao Liao
    • Solymar Negretti
    • Huw M. L. Davies
    Research
    Nature
    Volume: 533, P: 230-234
  • Catalyst-controlled site selectivity without relying on the influence of a directing group within the substrate is a major challenge in C–H functionalization. Now a catalyst is described that selectively functionalizes non-activated primary C–H bonds in the presence of a variety of other C–H bonds and functional groups.

    • Kuangbiao Liao
    • Yun-Fang Yang
    • Huw M. L. Davies
    Research
    Nature Chemistry
    Volume: 10, P: 1048-1055
  • The development of C–H functionalization methodology offers a new logic for chemical synthesis. Dirhodium tetracarboxylates have emerged as some of the most effective catalysts for these transformations, enabling site-selective and stereoselective insertion of transient metal carbenes into C–H bonds.

    • Huw M. L. Davies
    • Kuangbiao Liao
    Reviews
    Nature Reviews Chemistry
    Volume: 3, P: 347-360