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Showing 1–2 of 2 results
Advanced filters: Author: Laurent Nony Clear advanced filters

  • On-surface chemistry can overcome the limitations of in-solution synthesis but so far has been limited to metal substrates and unconventional mechanisms, thereby precluding a direct transposition of classic organic reactions. Herein, the authors report the photoinduced deoxygenation of dibenzothiophene S-oxide on insulating alkali halide surfaces in ultra-high vacuum.

    • Mélissa Hankache
    • Valentin Magné
    • Laurent Nony
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-9

  • On-surface polymerization is a promising technique to prepare organic functional nanomaterials, but it has remained difficult to carry out on insulating surfaces. Now, the photoinitiated radical polymerization of dimaleimide on KCl, initiated from a two-dimensional gas phase and guided by molecule–substrate interactions, has led to polymer fibres up to 1 μm long.

    • Franck Para
    • Franck Bocquet
    • Matthew B. Watkins
    Research
    Nature Chemistry
    Volume: 10, P: 1112-1117