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Showing 1–3 of 3 results
Advanced filters: Author: Lung-Wa Chung Clear advanced filters

  • Many methods exist for the atroposelective synthesis of axially chiral biaryls, but axially chiral styrenes are much less explored. Here the authors report an organocatalytic procedure for the synthesis of configurationally stable, axially chiral styrenes with high enantio- and diastereoselectivities.

    • Sheng-Cai Zheng
    • San Wu
    • Bin Tan
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-9

  • Hydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom. Here, the authors report the asymmetric rhodium-catalyzed hydroformylation of 1,2-disubstituted alkenylsilanes with excellent regioselectivity at the β position (relative to the silicon heteroatom) and enantioselectivity.

    • Cai You
    • Xiuxiu Li
    • Xumu Zhang
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-9