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Showing 1–2 of 2 results
Advanced filters: Author: M. Rübhausen Clear advanced filters

  • The origin of the two-dimensional electron gas at complex oxide interfaces is often explained by the polar catastrophe model, which involves a charge transfer mechanism. Using optical conductivity analysis, the authors assign and quantify the charge transfer, corroborating the polar catastrophe scenario.

    • T.C. Asmara
    • A. Annadi
    • A. Rusydi
    Research
    Nature Communications
    Volume: 5, P: 1-10

  • According to the entatic-state principle, distortions of the coordination geometry of a reacting compound can optimize the energies of starting and final states to improve reaction rates. Here, the entatic-state principle is observed to apply to photoactive copper complexes that have a constrained ligand geometry, resulting in very short charge-transfer state lifetimes.

    • B. Dicke
    • A. Hoffmann
    • S. Herres-Pawlis
    Research
    Nature Chemistry
    Volume: 10, P: 355-362