Nitriles can be hydrogenated with a variety of precious metal catalysts, yet there is a lack of heterogeneous systems based on affordable metals such as iron. Here, the authors report a silica-supported Fe/Fe–O core–shell catalyst with the ability to hydrogenate nitriles in the presence of aluminium additives.
- Vishwas G. Chandrashekhar
- Thirusangumurugan Senthamarai
- Matthias Beller