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Showing 1–2 of 2 results
Advanced filters: Author: Moritz Malischewski Clear advanced filters

  • The synthesis, structure and reactivity of room-temperature-stable [Cp(C6F5)5]+[Sb3F16]− is presented. Coordination of the cyclopentadienyl cation by [Sb3F16]− or C6F6 stabilizes the antiaromatic singlet state in the solid state. Calculated hydride and fluoride ion affinities of the [Cp(C6F5)5]+ cation are higher than those of the tritylium cation [C(C6F5)3]+.

    • Yannick Schulte
    • Christoph Wölper
    • Stephan Schulz
    Research
    Nature Chemistry
    Volume: 16, P: 651-657

  • Complexes of iron in high oxidation states play a pivotal role as active intermediates in numerous catalytic processes. Now, using a multimethod approach on a single molecular system, it has been shown that a stable high-valent Fe(VI) nitride can be converted to a reactive, superoxidized, heptavalent Fe(VII) nitride.

    • Martin Keilwerth
    • Weiqing Mao
    • Karsten Meyer
    ResearchOpen Access
    Nature Chemistry
    Volume: 16, P: 514-520