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Showing 1–2 of 2 results
Advanced filters: Author: Nikifar Lazouski Clear advanced filters

  • Lithium-mediated nitrogen fixation is a promising pathway to electrochemical ammonia synthesis, but the role of metallic lithium and its passivation layer are unclear. Here the authors employ cryogenic transmission electron microscopy to explore these components, finding that the proton donor is the key determinant of lithium reactivity.

    • Katherine Steinberg
    • Xintong Yuan
    • Yuzhang Li
    Research
    Nature Energy
    Volume: 8, P: 138-148

  • Non-polar gaseous reactants such as N2 and H2 exhibit low solubility and slow transport in non-aqueous solvents and conventional gas diffusion electrodes cannot avoid non-aqueous electrolyte penetration. Here, transport limitations and catalyst flooding in tetrahydrofuran are overcome by using a stainless steel cloth-based support for lithium-mediated ammonia synthesis paired with H2 oxidation.

    • Nikifar Lazouski
    • Minju Chung
    • Karthish Manthiram
    Research
    Nature Catalysis
    Volume: 3, P: 463-469