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Showing 1–2 of 2 results
Advanced filters: Author: Ole Bunjes Clear advanced filters

  • Thiolate groups are promising anchors to immobilize catalysts, particularly on coinage metal surfaces, but the anchor group’s impact on the local adsorption configuration of the catalyst is often overlooked. Here, the authors study a sulfurated derivative of the prominent Re(bpy)(CO)3Cl carbon dioxide reduction catalysts on a Ag(001) surface at room temperature.

    • Ole Bunjes
    • Alexandra Rittmeier
    • Martin Wenderoth
    ResearchOpen Access
    Communications Chemistry
    Volume: 7, P: 1-8

  • Catalytically active complexes adsorbed to noble metal surfaces hold potential for CO2 utilisation. Here, the mechanism of growth of fac-Re(bpy)(CO)3Cl on Ag(001) is shown to begin at well-oriented surface steps, with surface restructuring promoting the growth of long-range ordered assemblies.

    • Ole Bunjes
    • Lucas A. Paul
    • Martin Wenderoth
    ResearchOpen Access
    Communications Chemistry
    Volume: 5, P: 1-8