The small-angle X-ray scattering intensity from the coexisting concentrated phase was measured in a phase-separated aqueous solution of the thermosensitive block copolymer poly(2-isopropyl-2-oxazoline)-b-poly(2-ethyl-2-oxazoline) under amphiphilic conditions (50 °C). The concentrated phase was disordered with no sign of micro phase separation. In addition, the scattering from individual copolymer chains and their aggregates existing in the concentrated phase hardly contributed to the total scattering intensity of the phase-separated colloidal solution of the block copolymer.
- Masaaki Kondo
- Rintaro Takahashi
- Takahiro Sato