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Showing 1–2 of 2 results
Advanced filters: Author: Quentin Michaudel Clear advanced filters

  • Polymerization methods that control the cis/trans stereochemistry of repeating alkenes in polyalkenamers remain scarce. Now, an acyclic diene metathesis process has been developed that enables control over the stereochemistry of the polymer backbone. The method harnesses the reactivity of dithiolate Ru carbenes, in combination with cis,cis-diene monomers, to access several classes of polymers with tailored properties.

    • Ting-Wei Hsu
    • Samuel J. Kempel
    • Quentin Michaudel
    Research
    Nature Chemistry
    Volume: 15, P: 14-20

  • Structural and functional studies reveal how the bacterial flavoenzyme EncM catalyses the oxygenation–dehydrogenation dual oxidation of a highly reactive substrate, and show that EncM maintains a stable flavin oxygenating species that promotes substrate oxidation and triggers a rarely seen Favorskii-type rearrangement.

    • Robin Teufel
    • Akimasa Miyanaga
    • Bradley S. Moore
    Research
    Nature
    Volume: 503, P: 552-556