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Showing 1–4 of 4 results
Advanced filters: Author: Serguei Soubatch Clear advanced filters

  • Identifying reaction pathways is a major challenge in chemistry, and proves particularly difficult for surface reactions. Here the authors show that imaging the molecular orbitals with photoemission tomography provides insight into the structure of surface intermediates allowing their identification.

    • Xiaosheng Yang
    • Larissa Egger
    • F. Stefan Tautz
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-6

  • Typically for surface adsorption there is a direct relationship between interaction strength and geometric distance—a stronger interaction leads to a shorter distance between interacting objects. Here the authors show a case where a stronger interaction leads to a larger distance, and explain this apparent paradox.

    • Benjamin Stadtmüller
    • Daniel Lüftner
    • Christian Kumpf
    Research
    Nature Communications
    Volume: 5, P: 1-7

  • When a molecule interacts chemically with a metal, its orbitals hybridise with metal states to form the new eigenstates of the coupled system. Here, the authors show that in addition to overlap in real space and energy, hybridizing states must fulfil a momentum-matching condition.

    • Xiaosheng Yang
    • Matteo Jugovac
    • F. Stefan Tautz
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-9