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Showing 1–5 of 5 results
Advanced filters: Author: Shane G. Telfer Clear advanced filters
  • Interpenetration—in which two or more lattices are catenated—is common in metal–organic frameworks (MOFs). Now a deliberate synthesis of hetero-interpenetrated MOFs, with two distinct lattices, has been developed. It can combine the different properties of the two sublattices in one material, as demonstrated with chirality and catalytic activity, delivering an asymmetric catalyst.

    • David Perl
    • Seok J. Lee
    • Shane G. Telfer
    Research
    Nature Chemistry
    Volume: 15, P: 1358-1364
  • Metal–organic framework glasses have emerged as a new family of melt-quenched glass, but have yet to display the accessible porosity of their crystalline counterparts. Here, Bennett and colleagues report that glasses derived from ZIF-76 parent materials possess 4 – 8 Å pores and exhibit reversible gas adsorption.

    • Chao Zhou
    • Louis Longley
    • Thomas D. Bennett
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-9
  • Metal-organic framework adsorbents are promising materials for gas separation and purification. Herein, the authors present a metal-organic framework that selectively captures CO2 over small hydrocarbons; this separation is relevant for the purification of natural gas and industrial feedstocks.

    • Omid T. Qazvini
    • Ravichandar Babarao
    • Shane G. Telfer
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-8
  • The simultaneous high-pressure and high-temperature phase diagram of two MOFs, ZIF-4 and ZIF-62, is mapped. Crystalline, pressure- and temperature-amorphous, and liquid states are found, while melting temperature is found to decrease with pressure.

    • Remo N. Widmer
    • Giulio I. Lampronti
    • Thomas D. Bennett
    Research
    Nature Materials
    Volume: 18, P: 370-376
  • Interpenetration of metal–organic frameworks (MOFs) is a common phenomenon, in which a structure consists of two or more identical, entangled sub-lattices. Now, MOFs with variable, fractional degrees of occupancy of one of two sub-lattices have been prepared. The extent of interpenetration can be controlled either during synthesis or by autocatenation, a framework rearrangement process.

    • Alan Ferguson
    • Lujia Liu
    • Shane G. Telfer
    Research
    Nature Chemistry
    Volume: 8, P: 250-257