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Showing 1–2 of 2 results
Advanced filters: Author: Soji Shimizu Clear advanced filters

  • Little is known about interactions between two antiaromatic molecules. Here, the authors synthesised a cyclophane, in which two antiaromatic porphyrin moieties adopt a stacked face-to-face geometry with a distance shorter than the sum of the van der Waals radii of the atoms involved.

    • Ryo Nozawa
    • Jinseok Kim
    • Hiroshi Shinokubo
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-7

  • It has been proposed that stacking antiaromatic molecules can build three-dimensional aromaticity, but this claim has lacked experimental validation. Here the authors report that π–π stacked antiaromatic porphyrins display significantly reduced antiaromaticity in solid state and in solution.

    • Ryo Nozawa
    • Hiroko Tanaka
    • Hiroshi Shinokubo
    ResearchOpen Access
    Nature Communications
    Volume: 7, P: 1-7