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Showing 1–2 of 2 results
Advanced filters: Author: Stephanie Essafi Clear advanced filters

  • The iterative, reagent-controlled homologation of a boronic ester is used to create an ‘assembly line’ capable of synthesizing organic molecules that contain ten contiguous, stereochemically defined methyl groups and which have different shapes depending on the stereochemistry of those groups.

    • Matthew Burns
    • Stéphanie Essafi
    • Varinder K. Aggarwal
    Research
    Nature
    Volume: 513, P: 183-188

  • A general and broad-ranging stereospecific coupling of secondary and tertiary boronic esters with electron-rich aromatics is reported. The reaction involves initial formation of a boronate complex followed by activation of the electron-rich aromatic moiety by an electrophile, which triggers a stereospecific 1,2-migration and subsequent elimination/re-aromatization.

    • Amadeu Bonet
    • Marcin Odachowski
    • Varinder K. Aggarwal
    Research
    Nature Chemistry
    Volume: 6, P: 584-589