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Showing 1–7 of 7 results
Advanced filters: Author: Steve B. Maron Clear advanced filters

  • The parent diphosphene molecule is of fundamental interest, but its reactive nature renders it challenging to isolate, and current metal-stabilized derivatives are limited to complexes of p-/d-metals. Here, the authors introduce f-element diphosphene complexes, adding to f-element diazenes that were first reported over thirty years ago.

    • Jingzhen Du
    • Thayalan Rajeshkumar
    • Stephen T. Liddle
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-15

  • Despite their importance as mechanistic models for Haber Bosch ammonia synthesis from N2 and H2, high oxidation state terminal metal-nitrides are notoriously unreactive towards H2. Here, the authors report hydrogenolysis of a uranium(V)-nitride, which can occur directly or by Frustrated Lewis Pair chemistry with a borane ancillary.

    • Lucile Chatelain
    • Elisa Louyriac
    • Stephen T. Liddle
    ResearchOpen Access
    Nature Communications
    Volume: 11, P: 1-12

  • Disproportion of uranium(IV) is rare, as it is usually the stable product of uranium(III) or (V) disproportionation. Here, the authors report uranium(IV) disproportionation to uranium(III) and (V) revealing ligand and solvent control over a key thermodynamic property of uranium

    • Jingzhen Du
    • Iskander Douair
    • Stephen T. Liddle
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-12

  • An individualized, heterologous chimpanzee adenovirus (ChAd68) and self-amplifying mRNA-based neoantigen vaccine is safe and well tolerated in patients, warranting further studies to test its potential to rescue response to checkpoint blockade in tumors of low immune reactivity.

    • Christine D. Palmer
    • Amy R. Rappaport
    • Karin Jooss
    Research
    Nature Medicine
    Volume: 28, P: 1619-1629

  • Despite the burgeoning nature of uranium–ligand multiple bonding, analogous thorium complexes remain incredibly rare. Here the authors report evidence for a transient thorium–nitride species, which, together with data on parent imido derivatives, suggests that the pushing-from-below phenomenon may be more widespread than previously thought.

    • Jingzhen Du
    • Carlos Alvarez-Lamsfus
    • Stephen T. Liddle
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-13

  • The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within f-block chemistry.

    • Benedict M. Gardner
    • Christos E. Kefalidis
    • Stephen T. Liddle
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-10