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Showing 1–7 of 7 results
Advanced filters: Author: Taisuke Matsuno Clear advanced filters

  • Incommensurate pairing is a type of stereoisomerism, observed in carbon bilayers, that arises from the twisted orientations of the graphitic layers. Here, the authors create a finite molecular version of an incommensurate carbon bilayer in the form of two concentrically assembled cylindrical molecules.

    • Taisuke Matsuno
    • Yutaro Ohtomo
    • Hiroyuki Isobe
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-8

  • Mechanical motions in hybrid sp2/sp3 -hybrid nanocarbon peapods might lead to promising materials applications, but have been insufficiently explored. Here the authors demonstrate that a diamondoid molecule trapped inside a carbonaceous cylinder undergoes solid-state rotations at terahertz frequencies.

    • Taisuke Matsuno
    • Seiya Terasaki
    • Hiroyuki Isobe
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-7

  • Though dynamics of molecules are generally restricted by intermolecular contacts, C60 fullerene is able to rotate freely despite being tightly bound inside a molecular host. Here, the authors study the solid-state dynamics of this host-guest system to understand the anomalous relationship between tight association and low friction.

    • Taisuke Matsuno
    • Yusuke Nakai
    • Hiroyuki Isobe
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-5

  • The weak and directional CH-π hydrogen bond has rarely been exploited in the design of supramolecular complexes and molecular machinery. Here, the authors construct a bowl-in-tube complex stabilized solely by concyclic CH-π hydrogen bonds, and show that the guest exhibits single-axis rotational motion despite tight association with the host.

    • Taisuke Matsuno
    • Masahiro Fujita
    • Hiroyuki Isobe
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-8

  • Incommensurate double-wall carbon nanotubes give rise to unique stereochemistry originating from twisted stacks of hexagon arrays, but atomic-level studies of molecular analogues are hindered by the challenges in designing and synthesizing pairs of chiral cylindrical molecules. Here, a molecular version of incommensurate double-wall carbon nanotubes is designed by development of a roadmap of synthetically accessible chiral indices.

    • Hiroyuki Isobe
    • Yuki Kotani
    • Koki Ikemoto
    ResearchOpen Access
    Communications Chemistry
    Volume: 5, P: 1-9