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Showing 1–4 of 4 results
Advanced filters: Author: Tim Michaelsen Clear advanced filters

  • Crossed-beam reactive scattering experiments of a nucleophilic substitution reaction show a dynamic isotope effect with a remarkable deviation from quasiclassical calculations, which is evidence for quantum dynamics in this ion-molecule reaction.

    • Atilay Ayasli
    • Arnab Khan
    • Roland Wester
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-10

  • As the number of atoms involved in a reaction increases, so do the experimental and theoretical challenges faced when studying their dynamics. Now, using ion-imaging experiments and quasi-classical trajectory simulations, the dynamics of the polyatomic reaction F– + CH3CH2Cl have been studied and the competition between bimolecular nucleophilic substitution and base-induced elimination has been disentangled.

    • Jennifer Meyer
    • Viktor Tajti
    • Roland Wester
    Research
    Nature Chemistry
    Volume: 13, P: 977-981

  • The competition between chemical reactions critically affects our natural environment and the synthesis of new materials. Here, the authors present an approach to directly image distinct fingerprints of essential organic reactions and monitor their competition as a function of steric substitution.

    • Eduardo Carrascosa
    • Jennifer Meyer
    • Roland Wester
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-7