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Showing 1–3 of 3 results
Advanced filters: Author: Travis Dudding Clear advanced filters

  • Mechanistic studies of the hemilability of MIDA (N-methyliminodiacetic acid) boronates reveal the chameleonic behaviour of the BMIDA group. The superior migratory aptitude of BMIDA compared to hydride and the capacity to resemble a proton when nitrogen decoordinates from boron have now been exploited for the design of new boron transfer reactions.

    • C. Frank Lee
    • Diego B. Diaz
    • Andrei K. Yudin
    Research
    Nature Chemistry
    Volume: 10, P: 1062-1070

  • Glycomimetics are structural mimics of carbohydrates that can replicate their biological activity but have improved drug-like properties. Here, using proline-catalysed α-halogenation/aldol cascades, carbohydrate building blocks are readily assembled and then diversified into glycomimetics including imino- and carbasugars.

    • Michael Meanwell
    • Gaelen Fehr
    • Robert Britton
    ResearchOpen Access
    Communications Chemistry
    Volume: 4, P: 1-9