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Showing 1–3 of 3 results
Advanced filters: Author: Trevor W. Hayton Clear advanced filters

  • A complex featuring a uranium(VI) terminal nitride functional group has been isolated through mild oxidation, and shown to be highly reactive. Under photolysis, it converts into a compound that is capable of C–H bond activation.

    • Trevor W. Hayton
    News & Views
    Nature Chemistry
    Volume: 5, P: 451-452

  • Computational and spectroscopic studies of molecular lanthanide complexes have implicated 4f orbitals in metal–ligand bonding interactions. Now, a comparative study of isostructural d-block, actinide and lanthanide complexes has shown that 4f-orbital covalency enables ring-opening isomerization in a Ce(IV)–cyclopropenyl complex in the solid state, a reaction not observed for the other complexes studied.

    • Brett D. Vincenzini
    • Xiaojuan Yu
    • Eric J. Schelter
    Research
    Nature Chemistry
    Volume: 17, P: 961-967

  • Redox-switchable chelation is demonstrated for a carborane cluster molecule, leading to controlled chemical or electrochemical capture and release of uranyl in monophasic or biphasic model solvent systems.

    • Megan Keener
    • Camden Hunt
    • Gabriel Ménard
    Research
    Nature
    Volume: 577, P: 652-655