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Showing 1–4 of 4 results
Advanced filters: Author: Wujun Jian Clear advanced filters

  • Stereocontrol of C–O bond formation from a carbon-based radical is very difficult due to the rapid inversion of the carbon radical. Here the authors present a method to form chiral esters from conjugated dienes with copper and chiral PyBox ligands, likely proceeding via an allylic radical.

    • Xiaotao Zhu
    • Wujun Jian
    • Hongli Bao
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-9

  • Carboazidation of alkenes and alkynes holds the promise to construct valuable, functionalized molecules. Here, the authors report a general and efficient iron-catalyzed carboazidation of both alkenes and alkynes enabled by t-butyl perbenzoate.

    • Haigen Xiong
    • Nagarajan Ramkumar
    • Hongli Bao
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-7

  • Pt oxides are essential catalysts in many critical reactions, but are typically unstable and prone to evaporation above 700 K. A two-dimensional layered Pt oxide with exceptional thermal stability is introduced, capable of surviving at high temperatures.

    • Jun Cai
    • Liyang Wei
    • Zhu-Jun Wang
    ResearchOpen Access
    Nature Materials
    Volume: 23, P: 1654-1663

  • The carboazidation of olefins represents an effective strategy to introduce both carbon and nitrogen substituents into hydrocarbons, but asymmetric versions of this reaction remain elusive. Now, an iron-catalysed asymmetric radical carboazidation is introduced that yields chiral halogenated organoazides in high enantiomeric ratios.

    • Liang Ge
    • Huan Zhou
    • Hongli Bao
    Research
    Nature Catalysis
    Volume: 4, P: 28-35