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Advanced filters: Author: Yaroslav V. Tkachev Clear advanced filters

  • The direct C–H activation of inert C(sp3)–H bonds in a hydrocarbon chain is an attractive target in organic synthesis but C-H activation driven by vinyl carbocations remains underdeveloped. Here, the authors design a double C(sp3)–H functionalization of unactivated alkyl CH2 groups to produce substituted quaternary carbon stereocenter via insertion of vinyl carbocations.

    • Roman A. Novikov
    • Denis D. Borisov
    • Yury V. Tomilov
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-11