Here, the authors report a hydrostatic-pressure-driven anomalous enhancement of the spontaneous polarization of CuInP2S6 at room temperature, in contrast to the standard pressure-induced suppression of ferroelectricity. The polarization enhancement stems from the spatial instability of the Cu cations and increase of Cu occupancy at the interlayer site.
- Xiaodong Yao
- Yinxin Bai
- Jinlong Zhu
