The crystallization behavior of the ethylene, propylene and carbon monoxide/thermoplastic elastomer (EPCO/HY) blends in the static and dynamic states revealed that immiscible HY retarded the crystallization of EPCO without changing its crystal structure. The large difference in the elastic moduli of the two polymers at the crystallization temperature was the principal reason for the retardation process. The retardation of crystallization could be explained by steric hindrance or a shield effect of the HY phase on the growth of EPCO spherulites at a temperature near the crystallization temperature (Tc).
- Youngho Eom
- Jeongsik Bae
- Byoung Chul Kim