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Showing 1–3 of 3 results
Advanced filters: Author: Zhaowen Dong Clear advanced filters

  • Heavier group 14 carbene analogue display remarkable capability for small molecule activation but their application in redox catalysis remains elusive. Here, the authors report the synthesis and isolation of a stannylene with carbodiphosphorane ligand and characterize its catalytic activity in the hydrodefluorination reaction of fluoroarenes.

    • Zhuchunguang Liu
    • Zhijun Wang
    • Zhaowen Dong
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-8

  • Diazoolefins tend to be highly reactive compounds, and thus experimental evidence of these species is currently limited. Now, the reactivity and coordination chemistry of N-heterocyclic diazoolefins has been described. Diazoolefins are observed to form in reactions of N-heterocyclic olefins with nitrous oxide. The products benefit from resonance stabilization, enabling isolation on a preparative scale and comprehensive characterization.

    • Paul Varava
    • Zhaowen Dong
    • Kay Severin
    Research
    Nature Chemistry
    Volume: 13, P: 1055-1060

  • It remains a challenge to achieve a balance between performance and stability, as well as addressing the environmental impact of perovskite solar cells. Here, the authors propose a multimodal host-guest complexation strategy enabling these shortcomings to be addressed simultaneously.

    • Hong Zhang
    • Felix Thomas Eickemeyer
    • Michael Grätzel
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-11