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Polyimide-derived carbon molecule sieve membranes for gas separations

Polyimide-derived carbon molecular sieve (CMS) membranes mark an important step for various current, key energy-intensive separations. The excellent separation performance combined with economical scalability make CMS membranes ready to enable energy-transition-focused gas separations.

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Fig. 1: Key features and engineering of CMS membranes for industrial gas separations.
Fig. 2: CMS hollow-fiber formation options.

References

  1. Koros, W. & Zhang, C. Nat. Mater. 16, 289–297 (2017).

    Article  ADS  CAS  PubMed  Google Scholar 

  2. Zhang, C. & Koros, W. J. Adv. Mater. 29, 1701631 (2017).

    Article  Google Scholar 

  3. Liu, Z., Qiu, W. & Koros, W. J. Angew. Chem. Int. Ed. 61, e202210831 (2022).

    Article  CAS  Google Scholar 

  4. Hou, M. et al. J. Membr. Sci. 656, 120639 (2022).

    Article  CAS  Google Scholar 

  5. Flory, P. in Liquid Crystal Polymers I (ed. Platé, N. A.) Vol. 59, 1–36 (Springer, 1984).

  6. Iyer, G. M. & Zhang, C. ACS Mater. Lett. 5, 243–248 (2022).

    Article  Google Scholar 

  7. Hazazi, K. et al. Nat. Mater. 22, 1218–1226 (2023).

    Article  ADS  CAS  PubMed  Google Scholar 

  8. Haider, S., Lie, J. A., Lindbråthen, A. & Hägg, M.-B. Membranes 8, 105 (2018).

    Article  PubMed  PubMed Central  Google Scholar 

  9. Araújo, T., Andrade, M., Bernardo, G. & Mendes, A. J. Membr. Sci. 641, 119852 (2022).

    Article  Google Scholar 

  10. Oh, B., Seo, H., Choi, J., Lee, S. & Koh, D.-Y. Nat. Commun. 13, 4972 (2022).

    Article  ADS  CAS  PubMed  PubMed Central  Google Scholar 

  11. Touma, S. L. et al. Innovative gas treatment solutions for offshore systems. In Offshore Technology Conference Brasil D021S016R009 (OTC, 2019).

  12. Bhuwania, N. et al. Carbon 76, 417–434 (2014).

    Article  CAS  Google Scholar 

  13. Zhang, C., Kumar, R. & Koros, W. J. AIChE J. 65, e16611 (2019).

    Article  ADS  Google Scholar 

  14. Cao, Y., Liu, Z., Qiu, W. & Koros, W. J. Angew. Chem. Int. Ed. 62, e202303915 (2023).

  15. Zhang, C., Zhang, K., Cao, Y. & Koros, W. J. Ind. Eng. Chem. Res. 57, 16051–16058 (2018).

    Article  CAS  Google Scholar 

  16. Koros, W. J. & Lively, R. P. AIChE J. 58, 2624–2633 (2012).

Download references

Acknowledgements

We acknowledge the support by the Roberto C. Goizueta Chair fund, the US Department of Energy Grant DE‐FG02‐04ER15510, and Specialty Separations Center at Georgia Institute of Technology for assistance in equipment resource funds.

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Correspondence to William J. Koros.

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W.J.K. notes that Air Liquide has licensed the Georgia Institute of Technology V-treatment intellectual property (IP) mentioned in Fig. 2.

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Nature Chemical Engineering thanks Tonghua Wang for their contribution to the peer review of this work.

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Liu, Z., Cao, Y. & Koros, W.J. Polyimide-derived carbon molecule sieve membranes for gas separations. Nat Chem Eng 1, 119–123 (2024). https://doi.org/10.1038/s44286-023-00021-1

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