Anodic C(sp3)–H bond oxidative functionalization that involve C(sp3)–M, a C(sp3) radical or a C(sp3) cation intermediate with hydrogen evolution can be achieved by direct and indirect electrolysis. This Review discusses both strategies, and gives examples of the electrochemical methods developed for such functionalization reactions.
- Zhaoliang Yang
- Wenyan Shi
- Aiwen Lei