Large discrete 2D metallosupramolecules bridge the gap between small metallopolygons and infinite 2D metallopolymers, and are emerging platforms for the investigation of the structure–property–function relationships of 2D materials. This Review focuses on the design, synthesis and characterization of 2D metallosupramolecules, and presents a perspective on the future research directions.
- Heng Wang
- Yiming Li
- Xiaopeng Li