Identification of stratospheric volcanic eruptions in the geological record and their link to mass extinction events during the past 540 million years remains challenging. Here, the authors report unexpected, large mass-independent sulphur isotopic compositions of pyrite in Late Ordovician sedimentary rocks, which they suggest originates from stratospheric volcanism linked to the first pulse of the Late Ordovician mass extinction.
- Dongping Hu
- Menghan Li
- Yanan Shen