Table 1 Analysis of the transient XES signal.

From: Visualizing the non-equilibrium dynamics of photoinduced intramolecular electron transfer with femtosecond X-ray pulses

Model

t 0 (ps)

γ 0 (ps)

τ 1 (ps)

σ (ps)

P

A

1.5±0.3

0.66±0.02

—

1.5±0.3

0.04

B

0.05±0.13

0.67±0.02

1.9±0.5

0.52±0.41

0.50

  1. The fitting parameters were t0 (time 0), γ0 (initial excitation fraction), τ1 (free rate constant) and σ (width of the Gaussian broadening) for models A and B. The corresponding p parameters are given in the last column.
Back to article page