Table 2 List of varnish removal solutions and delivery system, with preparation and application

From: Evaluation of agar spray for the development of a green surfactant-free rigid emulsions

Sample

System

Tailored options

Preparation

Application

Clearance

Oil paint with dammar XVIII sec.(fragment)

Surfactant-free O/W micro- emulsion

Polysaccharide-based gel [spray on dammar varnish]

ASE1: Buffered waters with a pH 6 in Agar (3% w/w) and solvent DBE 5%

Buffer solution made with citric acid and sodium hydroxide.

Disperse the polysaccharide powder in buffered water, heat the solution at ~ 95 °C under stirring. The gel is cooled until it has gelled completely. The gel was dissolved again in a microwave. 5% of DBE was added in agar sol, mixed rapidly and inserted in spray gun. (Wall Sprayer Model W 450 by Wagner Spa)

Direct spray application

Agar containing buffered water and 5% DBE was sprayed onto the dammar varnish. The agar temperature was selected based on the room’s temperature and relative humidity conditions during application. This created a uniform gel layer approximately 2 mm thick over a 3 × 3 cm area, which was left in place for 2 minutes. The gel was then gently peeled away from the surface

Not required for pure hydrogels. When uploaded with active agents, involve the application of the same gel with deionized water (pH 6) for the same period. The gels can transfer a thin layer of liquid onto the surface, which can be removed by blotting the gel well before application; equally the paint surface can be lightly blotted after application if appropriate

As above

As above

ASE2: as above solvent DBE 10%

As above. 10% of DBE was added in agar sol, mixed rapidly and inserted in spray gun

Direct spray application-

Agar containing the buffered water and 10% of DBE was sprayed on dammar varnish. As above

As above

As above

As above

ASE3: as above solvent DBE 15%

As above. 15% of DBE was added in agar sol, mixed rapidly and inserted in spray gun

Direct spray application-

Agar containing the buffered water and 15% of DBE was sprayed on dammar varnish. As above

As above

Oil paint with dammar XVIII sec.(fragment)

Buffer solution in Polysaccharide-based gel [spray on plate]

ASE1: Buffered waters with a pH 6 in Agar (3% w/w) and solvent DBE 5%

Buffer solution made with citric acid and sodium hydroxide.

Disperse the polysaccharide powder in buffered water, heat the solution at ~ 95 °C under stirring. The gel is cooled until it has gelled completely. The gel was dissolved again in a microwave. 5% of DBE was added in agar sol, mixed rapidly and inserted in spray gun. (Wall Sprayer Model W 450 by Wagner Spa)

Indirect spray application-

Agar containing buffered water and 5% DBE was sprayed onto a plate. After blotting with Whatman filter paper, a spray gel piece, measuring 3 cm in diameter and 2 mm thick, was placed on the oil paint with dammar for 2 minutes. Light finger pressure was applied to optimize adhesion. After the contact time, the gel was then gently peeled away from the surface.

Not required for pure hydrogels. When uploaded with active agents, involve the application of the same gel with deionized water (pH 6) for the same period. The gels can transfer a thin layer of liquid onto the surface, which can be removed by blotting the gel well before application; equally, the paint surface can be lightly blotted after application if appropriate

As above

As above

ASE2: as above solvent DBE 10%

As above. 10% of DBE was added in agar sol, mixed rapidly, and inserted in spray gun

Indirect spray application-

Agar containing the buffered water and 10% of DBE was sprayed on plate. As above

As above

As above

As above

ASE3: as above solvent DBE 15%

As above. 15% of DBE was added in agar sol, mixed rapidly and inserted in spray gun

Indirect spray application-

Agar containing the buffered water and 15% of DBE was sprayed on plate. As above

As above