Table 4 The fragment information of sample C55-6 from the Py-GC/MS analysis

From: Investigation on gilding materials and techniques of murals in Cave 55 at Mogao Grottoes

No.

Retention time/min

m/z

Pyrolysis products identified

1

1.311

202

Pyrene

2

1.472

204

Pyrene,4,5-dihydro-

3

1.787

97

2-Methyl-3-oxobutyronitrile

4

2.248

78

Benzene

5

2.402

128

(3S)-(-)-3-Acetamidopyrrolidine

6

2.753

132

1,7-Heptanediol

7

2.980

121

1-Cyclohexene-1-acetonitrile

8

3.097

79

Pyridine

9

3.148

67

Pyrrole

10

3.302

92

Toluene

11

4.503

126

2-Octyn-1-ol

12

4.891

124

9-Oxabicyclo[6.1.0]non-4-ene

13

5.623

126

2-Octyn-1-ol

14

7.132

150

Bicyclo[3.3.1]non-6-ene-3, 9-dione

15

8.245

121

Benzaldehyde,oxime,(Z)-

16

10.434

168

Tricyclo[5.2.1.0(1,5)]decane-8,9-diol

17

13.590

210

Acetamide,N-methyl-N-[4-(3-hydroxypyrrolidinyl)-2-butynyl]-

18

16.724

238

Geranyl isovalerate

19

17.178

238

Geranyl isovalerate

20

18.979

240

Cyclopentadecanone,2-hydroxy-

21

19.169

344

Benzene,(3-octylundecyl)-

22

20.714

314

Ethanol,2-(octadecyloxy)-

23

24.639

240

Tetradecane,2,6,10-trimethyl-

24

28.344

186

Diketodipyrrole