Table 2 O2 consumption and DIC and TA production during sequential aerobic respiration, sulfate reduction and carbonate mineral dissolution in bottom waters45, 83

From: Redox reactions and weak buffering capacity lead to acidification in the Chesapeake Bay

Redox

Δ[O2] ( μmol kg−1)

ΔDIC ( μmol kg−1)

ΔTA ( μmol kg−1)

ΔTA/ΔDIC

pH

Ωarag

AR

(CH2O)106(NH3)16(H3PO4) + 106O2 ↔ 106CO2 + 16HNO3 + H3PO4 + 122H2O

−(16+1)/106 = −0.16

  
 

0 (100%)

0

0

 

8.055

1.56

 

−58 (75%)

+45

−7.2

 

7.859

1.05

 

−117(50%)

+90

−14.4

 

7.629

0.65

 

−174(25%)

+134

−21.5

 

7.421

0.40

 

−231.7(0%)

+178.0

−28.5

 

7.237

0.26

SR

(CH2O)106(NH3)16(H3PO4)  + 53SO4 2− → 106HCO3  + 53H2S + 16NH3 + H3PO4

(106+16−1)/106 = 1.142

  
 

0

+70.0

+80.6

 

7.199

0.25

CD

CaCO3 + CO2 + H2O → Ca2+  + 2HCO3

2/1

  
 

0

+57.6

+115.3

 

7.368

0.38

Total

−231.7

+305.6

+167.3

   
  1. AR, aerobic respiration; CD, carbonate dissolution; DIC, dissolved inorganic carbon; SR, sulfate reduction; TA, total alkalinity. The last columns listed the expected pH and aragonite mineral saturation state (Ωarag) values at the end of each step. pH and Ωarag values are also calculated at the initial and mid-points of O2 consumption (or % of O2 saturation). For simultaneous reactions at low pH and Ωarag, see the text. The calculation steps and results are detailed in the Methods. Note for a more stable carbonate mineral, calcite, Ωcalcite = 1.5 × Ωarag