Table 1 Vibrational frequencies (ν, cm−1) and IR intensities (km mol−1) of the linear and monocyclic \({{\rm C}}_{10}^ -\) and vibrational frequencies (ν, cm−1) of the transition state and linear and monocyclic C10
From: Ultraslow isomerization in photoexcited gas-phase carbon cluster \({{\rm C}}_{10}^ -\)
Linear \({{\bf C}}_{\bf 10}^ -\) | Monocyclic \({{\bf C}}_{\bf 10}^ -\) | Transition state | Linear C10 | Monocyclic C10 | ||
|---|---|---|---|---|---|---|
ν | IR intensity | ν | IR intensity | ν | ν | ν |
43.605 | 14.553 | 138.004 | 0.249 | −247.523 | 40.780 | 181.708 |
44.006 | 13.072 | 158.096 | 3.312 | 76.152 | 40.780 | 181.709 |
111.811 | 0.000 | 213.593 | 1.714 | 114.431 | 104.723 | 235.480 |
114.446 | 0.000 | 240.287 | 0.000 | 151.151 | 104.723 | 235.480 |
198.057 | 15.417 | 355.499 | 7.992 | 181.313 | 182.211 | 436.265 |
207.335 | 9.534 | 374.256 | 59.051 | 248.411 | 182.211 | 454.220 |
279.190 | 0.000 | 378.483 | 7.721 | 250.937 | 259.634 | 454.220 |
279.737 | 0.000 | 467.656 | 3.876 | 381.122 | 259.634 | 455.301 |
381.226 | 2.390 | 473.347 | 0.000 | 400.399 | 370.731 | 498.482 |
400.609 | 0.586 | 479.978 | 57.232 | 407.459 | 370.731 | 498.482 |
412.310 | 0.000 | 491.871 | 0.000 | 453.680 | 419.938 | 510.200 |
474.943 | 0.000 | 499.407 | 0.246 | 466.981 | 479.901 | 510.200 |
501.504 | 0.000 | 509.766 | 0.049 | 486.891 | 479.901 | 568.093 |
512.563 | 2.462 | 575.082 | 37.140 | 499.973 | 524.899 | 568.093 |
514.031 | 0.000 | 823.026 | 4.011 | 565.545 | 524.899 | 856.311 |
549.732 | 0.992 | 958.910 | 72.907 | 792.578 | 537.645 | 1081.477 |
563.845 | 0.000 | 1057.318 | 99.878 | 926.220 | 537.645 | 1081.477 |
796.017 | 41.744 | 1351.854 | 0.064 | 1199.552 | 810.449 | 1482.270 |
1154.220 | 0.000 | 1434.570 | 9.352 | 1392.925 | 1173.219 | 1506.370 |
1480.829 | 49.127 | 1530.446 | 32.001 | 1783.915 | 1506.340 | 1506.370 |
1912.916 | 0.000 | 1704.052 | 10.765 | 1882.131 | 1811.578 | 1962.315 |
2003.757 | 2351.481 | 1955.243 | 226.385 | 1918.078 | 2004.072 | 1962.315 |
2114.309 | 0.000 | 1998.975 | 315.677 | 2038.974 | 2086.088 | 2062.828 |
2179.331 | 0.000 | 2102.314 | 267.150 | 2110.288 | 2173.576 | 2062.829 |
2214.838 | 3382.104 | 2207.694 | ||||
