Table 1 Fit parameters

From: Exploiting limited valence patchy particles to understand autocatalytic kinetics

System

ΔUc/10−20(J)

ΔUa/10−20(J)

n ∞

DGEBA-mPDA

9.6 ± 0.1

9.1 ± 0.1

1.34 ± 0.02

DGEBA-BSA

9.6 ± 0.2

9.4 ± 0.1

1.45 ± 0.07

DGEBA-3DCM

11.9 ± 0.3

12.1 ± 0.3

1.47 ± 0.02

DGEBA-DETA

10.7 ± 0.1

10.9 ± 0.1

1.38 ± 0.02

DGEBA-CHA

9.7 ± 0.2

9.9 ± 0.2

1.65 ± 0.04

DGEBA-DDM

9.6 ± 0.2

9.1 ± 0.2

0.71 ± 0.02

  1. Activation enthalpy per single bond mediated by the initially present catalyst (ΔUc) and by the autoproduced catalyst (ΔUa), and the limiting value of n for different epoxy–amine systems.
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